Hao Yan（Lecturer）

Published：2022-10-24Author：王兆兴Number of Visits：47

  


  Name：

Hao Yan



Academic Title：

Lecturer


Advisor Type：

-


  Department：

Department of   Chemical Engineering


Research Interests：

Energy and chemical industry (oxidation and ammoniation of alcohols)


  E-Mail：

haoyan@upc.edu.cn


  Telephone：

+8618353244781






◎Educational Background


2011-2015, major in chemical   engineering and technology, China University of Petroleum (East China)， Bachelor of Engineering

2015-2017, major in chemical   engineering and technology, China University of Petroleum (East China)   (Master's degree and doctor's degree)，Master of Engineering (Master's degree and   doctoral degree)

2017-2020, State Key Laboratory of heavy oil, China   University of Petroleum (East China) ，doctor (Supervisor: Professor Chaohe Yang)











◎Work   Experience


2020-2022: Post Doctoral in Department   of chemical engineering, School of chemical engineering, China University of   Petroleum (East China) (Supervisor: Professor Xiang Feng)

(foreign cooperation tutor Professor   Ning Yan, National University of Singapore)










◎Research   Direction


The applicant's doctor has been   engaged in the research and development of catalysts in polyol oxidation, ammonia   oxidation and ammoniation and catalytic cracking. The research idea is DFT   theoretical calculation - catalyst design - Reaction Kinetics - process   simulation and amplification. The specific research contents are as follows:

（1） Exploration of micro reaction kinetics:   through DFT theoretical calculation, solve the polyol molecules and petroleum   hydrocarbon molecules downstream of Petrochemical / coal chemical industry   and the elementary reaction steps on the catalyst surface, obtain the   activation energy and rate constant, summarize the scale relationship between   different substrate binding energy and transition state energy, and establish   the volcanic map for catalyst activity prediction, Then, combined with the   experimental data or pilot test data, the reaction kinetic models of polyol   oxidation (ammonia oxidation and ammoniation) and catalytic cracking of   petroleum hydrocarbons are established based on the molecular scale, which   provides a theoretical basis for the directional construction of high-performance   catalysts;

（2） Directional design of polyol oxidation   catalyst: the structure-activity relationship between acid-base, pore   structure and catalytic performance is established by adjusting the structure   of molecular sieve / oxide support; By introducing a variety of metal active   components to form different catalytic active sites (monatomic active sites,   alloy active sites and interfacial active sites, etc.), the catalytic   performance of polyol conversion and hydrocarbon cracking was improved.

The above research results have been   widely recognized by peers. The applicant has published more than 30 academic   papers in famous journals at home and abroad, of which the first/corresponding   author in Angew. Chem. Int. Ed.、ACS. Catal.、Appl. Catal.   B-Environ.、J. Catal.、Green Chem.、AIChE. J.、Chem. Eng. Sci. and applied for 13 patents. The   applicant won the 2020 China Postdoctoral foreign exchange project, went to   study in the team of Professor Ning Yan of the National University of   Singapore. Presided over 5 projects including the youth fund of the National   Natural Science Foundation of China and the youth fund of the Natural Science   Foundation of Shandong Province; He won the nomination Award for excellent   doctoral thesis of Jingbo in chemistry, chemical engineering and materials,   the excellent oral report award of 21st Chinese Zeolite Conference,   etc.











◎Research Project


[1] National   Natural Science Foundation of China; In research; Study on the interface   structure regulation of Pt MOX catalyst and its mechanism of enhancing   glycerol synthesis; 2022-1-1 to 2024-12-31; No.: 22108305;

 

[2] Natural   Science Foundation of Shandong Province; In research; Construction of high   efficiency Pt based catalyst with rich acid-base sites on the surface and its   application in the catalytic oxidation of glycerol; 2022-1-1 to 2024-12-31;   No.: ZR2021QB076;

 

[3] China Postdoctoral   international exchange program; In research; Study on size effect of high   efficiency Pt based catalyst in biomass polyol oxidation system; 2021-1-1 to   2023-8-31; No.: 2020072;

 

[4] Qingdao   Postdoctoral Funded Project; In research; Directional design and reaction   mechanism of efficient and cheap Mn based catalyst for selective oxidation of   glycerol; From December 31, 2021 to August 31, 2023; No.: qdyy20200073;

 

[5] Independent   Innovation Research Projects; In research; Design of efficient and cheap   catalyst for selective oxidation of glycerol and Study on reaction mechanism;   From December 31, 2021 to August 31, 2023; No.: 20CX06095A;

 

[6]   Independent Innovation Research Projects; Conclusion; Study on the mechanism   of selective oxidation of glycerol on Pt supported mesoporous molecular   sieve; No.: 18CX067A.










◎Representative Papers and Patents


1.Paper

[1] Yan Hao, Zhao Mingyue, Feng Xiang*, Zhao Siming, Zhou Xin, Li   Shangfeng, Zha Minghao, Meng Fanyu, Chen Xiaobo, Liu, Yibin*, Chen De* and   Yang Chaohe, PO43- Coordinated Robust Single-Atom   Platinum Catalyst for Selective Polyol Oxidation [J]. Angewandte Chemie International   Edition, 2022, doi:10.1002/anie.202116059R2.

[2] Yan Hao, Yao Shuang, Zhang Tong, Li Delong, Tang Xiaoyu, Chen   Mengxin, Zhou Yixuan, Zhang Mingrui, Liu Yibin*, Zhou Xin, Feng Xiang*, Chen   Xiaobo, Yang Chaohe, Promoting catalytic transfer hydrodecarbonylation of   methyl stearate over bimetallic CoNi/HAP catalysts with strong electronic   coupling effect [J]. Applied Catalysis B:

[3] Yan Hao, Shen Qi, Sun Yinghao, Zhao Siming, Lu Ruilong, Gong   Mengcong, Liu Yibin, Zhou Xin*, Jin Xin, Feng Xiang*, Chen Xiaobo, Chen De   and Yang Chaohe, Tailoring Facets of α-Mn2O3   Microcrystalline Catalysts for Enhanced Selective Oxidation of Glycerol to   Glycolic Acid [J]. ACS Catalysis, 2021: 6371-6383.

[4] Yan Hao, Yao Shuang, Wang Jinyao, Zhao Siming, Sun Yinghao, Liu   Mengyuan, Zhou Xin, Zhang Guangyu, Jin Xin, Feng Xiang, Liu Yibin, Chen   Xiaobo, Chen De and Yang Chaohe. Engineering Pt-Mn2O3   interface to boost selective oxidation of ethylene glycol to glycolic acid   [J]. Applied Catalysis B: Environmental, 2021, 284: 119803.

[5] Yan Hao, Yao Shuang, Yin Bin, Liang Wei, Jin Xin, Feng Xiang, Liu   Yibin, Chen Xiaobo and Yang Chaohe. Synergistic effects of bimetallic PtRu/MCM-41   nanocatalysts for glycerol oxidation in base-free medium: Structure and   electronic coupling dependent activity[J]. Applied Catalysis B:   Environmental, 2019, 259: 118070.

[6] Yan Hao, Qin Hansong, Feng Xiang, Jin Xin, Liang Wei, Sheng Nan,   Zhu Chao, Wang Hongmei, Yin Bin, Liu Yibin, Chen Xiaobo and Yang Chaohe.   Synergistic Pt/MgO/SBA-15 nanocatalysts for glycerol oxidation in base-free   medium: Catalyst design and mechanistic study[J]. Journal of Catalysis,   2019, 370: 434-446.

[7] Yan Hao, Yao Shuang, Liang Wei, Zhao Siming, Jin Xin, Feng Xiang,   Liu Yibin, Chen Xiaobo and Yang Chaohe. Ni-Co Oxide Catalysts with Lattice   Distortions for Enhanced Oxidation of Glycerol to Glyceric acid,   Journal of Catalysis, 2019.

[8] Yan Hao, Yao Shuang, Zhao Siming, Liu Mengyuan, Zhang Wenxiang,   Zhou Xin, Zhang Guangyu, Jin Xin, Liu Yibin, Feng Xiang, Chen Xiaobo, Chen   De, Yang Chaohe. Insight into the basic strength-dependent catalytic   performance in aqueous phase oxidation of glycerol to glyceric acid[J]. Chemical   Engineering Science, 2021, 230: 116191.

[9] Yan Hao, Yao Shuang, Liang Wei, Feng Xiang, Jin Xin, Liu Yibin,   Chen Xiaobo and Yang Chaohe. Selective oxidation of glycerol to carboxylic   acids on Pt (111) in base-free medium: A periodic density functional theory   investigation[J]. Applied Surface Science, 2019, 497: 143661.

[10] Yan Hao, Qin Hansong, Liang Wei, Jin Xin, Zhang Yashuang, Feng   Xiang, Liu Yibin, Chen Xiaobo and Yang Chaohe. Enhanced performance of   bimetallic PtCo/MCM-41 catalysts for glycerol oxidation in base-free   medium[J]. Catalysis Science & Technology, 2019, 9(18): 4909-4919.

[11] Yan Hao, Zhao Siming, Yao Shuang, Liang Wei, Feng Xiang, Jin Xin,   Chen Xiaobo, Liu Yibin and Yang Chaohe. Influence of Lewis acid on activity   and selectivity of Pt/MCM-41 (Al) catalysts for oxidation of C3 polyols in   base-free medium[J]. Industrial & Engineering Chemistry   Research, 2019.

[12] Yan Hao, Feng Xiang, Liu Yibin, Yang Chaohe and Shan Honghong.   Catalytic cracking of acetic acid and its ketene intermediate over HZSM-5   catalyst: A density functional theory study[J]. Molecular Catalysis,   2017, 437: 11-17.

[13] 闫昊, 刘熠斌, 冯翔, 杨朝合, 山红红. 基于结构导向集总的废弃油脂催化裂化分子尺度动力学模型[J]. 化工学报, 2017, 68(4): 1407-1414.










◎Representative Works











◎Awards and Honors


 

(1) In 2020, he   was supported by the project sent by China Postdoctoral international   exchange program to exchange with the National University of Singapore;

(2) In 2020,   he won the nomination Award for Excellent Doctoral Dissertation of Jingbo in   chemistry, chemical industry and materials

(3) Won the   excellent oral report award of the 21st Chinese Zeolite Conference in 2021;

 










◎Courses Offered












◎Student Training


1.Supervise   Postgraduate Students

Assist and   guide 4 masters.

 

2.Typical   student：

Patriotic,   hardworking, with a certain level of foreign language knowledge and good   communication skills









◎Part-time Academic Job


Served as   reviewer of ACS Catalysis、Applied Catalysis B: Environmental、Molecular Catalysis and other   important international journals;